YKL and FIL carried out the PL analysis. CHC participated in the design of the study. YLC, CWL, JYJ, KHW, and HCK conceived the study and organized the final version of the paper. All authors read and approved the final manuscript.”
“Background Dinaciclib clinical trial Selective oxidation of alcohols to more valuable aldehydes, ketones, and carboxylic acids is of great importance to both the fine chemical industry and academia . Numerous stoichiometric oxidizing reagents have been involved to accomplish this transformation,
such as dichromate and permanganate. However, these reagents have many drawbacks, such as being toxic, expensive, and un-recyclable. Thus, the developments of a heterogeneous solid catalyst that can use molecular oxygen as Ilomastat nmr a primary oxidant have attracted much more attention. In this context, a series of noble metal supported catalysts for aerobic oxidation of alcohols have been exploited over the last decades. Among the noble metal supported catalysts, gold supported catalysts have been paid more and more attention, owing to their unique catalytic properties under mild conditions,
such as CO oxidation, hydrocarbon combustion, selective oxidation, and water gas shift reaction [2–5]. It is generally accepted that the catalytic performance of the gold catalysts strongly depended on not only the size of the gold particles but also the nature of the support material, the preparation method, and the activation procedure during the synthetic process . As supports, metal oxides have been employed, giving outstanding performance because of their facile activation of molecular oxygen [2, 7, 8]. At the same time, liquid-phase alcohol oxidation requires addition of soluble bases (metal carbonates, acetates, or borates), especially when inert supports such as silica, carbon, or polymers are used to disperse gold . Halloysite nanotubes (HNTs) (Al2Si2O5(OH)4 · 2H2O), hydrated layered aluminosilicates of the kaolinite group, containing octahedral gibbsite Al(OH)3 learn more and tetrahedral SiO4 sheets
(i.e., halloysite nanotubes), possess a hollow cylinder formed by multiply rolled layers . Because of their structural features, they offer a potential application as support for catalytic composites and the additive for reinforcing polymers with remarkable, improved mechanical properties and dispersibility. Recently, Yang et al. reported Pd nanoparticles deposited on HNTs nanocomposite for hydrogenation of styrene with enhanced catalytic VS-4718 in vivo activity . They cast a new light on using HNTs as catalyst support. Herein, we reported the synthesis of Au/HNTs catalyst and the structure of the catalyst was characterized. The as-synthesized Au/HNTs catalyst showed high catalytic activity for solvent-free oxidation of benzyl alcohol. Methods In a typical procedure, 3.6 g urea was dissolved in 200 mL of 1.46 mmol L−1 HAuCl4 solution at room temperature. An amount of 0.